Experiments for better teaching

The Plumbum Cell

T/P

time requ.: 15 minutes.
objective: Model of a car battery.
material:
  • beaker 150ml
  • battery 4.5 volts or DC power supply
  • crocodile clamps
  • multimeter
  • electrode support
  • connection cables
  • electric motor U<2V
chemicals:
  • 2 lead stripes

         

  • sulfuric acid w=20%

         

procedure 1: Fill the beaker three quarters of sulfuric acid. Place two stripes of lead into solution without touching each other. Connect them to the battery and electrolyze solution for some minutes.
observation 1: One strip turns brown.
interpretation 1: Through oxidation there is obtained brown plumbum(IV)-oxide on one electrode, through reduction on the other electrode plumbum metal (disproportioning).
procedure 2: Take the battery away and measure the voltage.
observation 2: U ~ 2V
interpretation 2: Through oxidation and reduction the lead electrodes were polarized to obtain a plumbum secondary cell. 6 of such cell serially connected together will form a car accumulator (U=12V).
procedure 3: Connect with the electromotor.
observation 3: The motor runs.
disposal of: Fill sulfuric acid into a flask and reuse for same experiment.
source: from Barke, H.-D. et al.: One Hundred Chemistry-Experiments to Avoid Chalk and Talk; University of Muenster, 2004.

  

  

  

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Didaktik der Chemie
Universität Bayreuth