Experiments for better teaching

Alcohols I: Cerium Test for Alcohol Group

T/P

time requ.: 10 minutes.
objective: Identification of the alcohol group
material:
  • beaker 100ml
  • magnetic stirrer
  • magnetic stirring bar
  • spatula 10mm for powders
  • test tube d=18mm
  • stopper
  • test tube stand
  • 2-5 teat pipettes
  • graded cylinder 50ml
chemicals:
  • ceric ammonium nitrate
  • nitric acid c=2mol/l
                     
  • ethanol     
  • acetic acid
  • distilled water
  • ethyl acetate
  • acetone
  • octane
preparation: Note: adapt volume of stock solution to the estimated number of tests you plan. For about 30 tests: Prepare a stock solution by dissolving 10g ceric ammonium nitrate in 25ml 2M nitric acid.
procedure 1: Dilute 1ml reagent with 2ml water. Add 5 drops of the unknown sample and shake.
procedure 2:

Make blank tests with positive reacting compounds (ethanol) and with negative reacting compounds (e.g. hydrocarbons, carbonic acids, esters, ketones).

observation: If the sample contains an alcohol, the colour will change from yellow to orange/red.
disposal of: Heavy metal solutions.
source: after Barke, H.-D. et al.: One Hundred Chemistry-Experiments to Avoid Chalk and Talk; University of Muenster, 2004.

© Walter.Wagner ät uni-bayreuth.de, Stand: 01.06.11

Didaktik der Chemie
Universität Bayreuth